N-Sulfonated-N-Heterocycles: synthesis, chemistry, and biological applications

Media type: Book

Title: N-Sulfonated-N-Heterocycles : synthesis, chemistry, and biological applications

Contributor: Elgemeie, Galal H. [VerfasserIn]; Azzam, Rasha A. [MitwirkendeR]; Zaghary, Wafaa A. [MitwirkendeR]; Aly, Ashraf A. [MitwirkendeR]; Metwally, Nadia H. [MitwirkendeR]; Sarhan, Mona O. [MitwirkendeR]; Abdelhafez, Elshimaa M. [MitwirkendeR]; Elsayed, Rasha E. [MitwirkendeR]

imprint: San Diego: Elsevier, 2022

Extent: xiv, 507 Seiten; Illustrationen

Language: English

ISBN: 9780128221792

RVK notation: VK 7200 : Allgemeines

Keywords: Heterocyclic compounds ; Sulfonation ; Electronic books ; Composés hétérocycliques

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Footnote: Description based on publisher supplied metadata and other sources

Description: Front Cover -- N-Sulfonated-N-Heterocycles -- Copyright Page -- Contents -- About the authors -- 1 Synthesis of N-sulfonated aziridines -- 1.1 Introduction -- 1.2 Synthesis of N-sulfonated aziridines via transferring of nitrogen to alkenes -- 1.2.1 The addition of nitrene species to alkenes -- 1.2.1.1 Nitrene transfer reactions using sulfonylimino iodinanes as nitrene precursors -- 1.2.1.2 Nitrene transfer reactions using sulfonamides as nitrene precursors -- 1.2.1.3 Nitrene transfer reactions using N-sulfonyl azides as nitrene precursors -- 1.2.1.4 Nitrene transfer reactions using haloamine-T as nitrene precursors -- 1.2.2 The addition of nitrogen-centered radical species to alkenes -- 1.3 Synthesis of N-sulfonated aziridines via transferring of carbon to N-sulfonyl imines -- 1.3.1 Direct aza-Darzens reaction -- 1.3.2 Reaction of N-sulfonyl imines with sulfonium ylides -- 1.4 Synthesis of N-sulfonated aziridines via intramolecular cyclization of amine derivatives -- References -- 2 Chemistry of N-sulfonated aziridines and their use in polymerization reactions -- 2.1 Introduction -- 2.2 Chemistry of N-sulfonated aziridines -- 2.2.1 Ring-opening of N-sulfonated aziridines to acyclic amine derivatives -- 2.2.1.1 To β-phenylethylamine derivatives -- 2.2.1.2 To vicinal diamines -- 2.2.1.3 To allyl amines and enamines -- 2.2.1.4 To Ketimines -- 2.2.2 Ring-opening of N-sulfonated aziridines to other cyclic N-sulfonated aza-heterocycles -- 2.2.2.1 To N-sulfonated four-membered heterocycles -- 2.2.2.2 To N-sulfonated five-membered heterocyclic ring -- 2.2.2.3 To N-sulfonated six-membered heterocyclic ring -- 2.2.2.4 To N-sulfonated seven-membered heterocyclic ring -- 2.3 Uses of N-sulfonated aziridines in living aza-anionic polymerization -- 2.3.1 Bis(trimethylsilyl)amides-catalyzed anionic ring-opening polymerization of N-sulfonated aziridines.

N-Sulfonated-N-Heterocycles : synthesis, chemistry, and biological applications

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