• Media type: E-Article
  • Title: Bridging the Analytical Gap Between Gas Treatment and Reactor Plants in Carbon2Chem®
  • Contributor: Hegen, Oliver; Salazar Gómez, Jorge Iván; Grünwald, Christina; Rettke, Alina; Sojka, Martha; Klucken, Christian; Pickenbrock, Jens; Filipp, Jan; Schlögl, Robert; Ruland, Holger
  • imprint: Wiley, 2022
  • Published in: Chemie Ingenieur Technik
  • Language: English
  • DOI: 10.1002/cite.202200015
  • ISSN: 0009-286X; 1522-2640
  • Keywords: Industrial and Manufacturing Engineering ; General Chemical Engineering ; General Chemistry
  • Origination:
  • Footnote:
  • Description: <jats:title>Abstract</jats:title><jats:p>The use of purified process gases as feedstock for subsequent processes requires a detailed verification of the gas purity to ensure long lifetimes of applied catalysts. Herein, the analytical infrastructure for the measurements of the cleaned gases is presented. An overview of all sampling points for the off‐ and on‐line analysis is given. The detailed decryption of the composition of the cleaned blast furnace gas, its main components as well as its traces are presented. Thereby, over 99 % of the overall signal strength of this complex gas matrix measured with a proton transfer reaction mass spectrometer with H<jats:sub>3</jats:sub>O<jats:sup>+</jats:sup> as reagent ion could be revealed. Furthermore, by the example of the catalyst poison H<jats:sub>2</jats:sub>S, the necessity of monitoring continuously the gas matrix for certain compounds was proven.</jats:p>