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Media type:
E-Article
Title:
Direct spectroscopic evidence for the high-spin state of dioxidomanganese(v)
Contributor:
Ablyasova, Olesya S.;
Zamudio-Bayer, Vicente;
Flach, Max;
da Silva Santos, Mayara;
Lau, J. Tobias;
Hirsch, Konstantin
Published:
Royal Society of Chemistry (RSC), 2024
Published in:
Physical Chemistry Chemical Physics, 26 (2024) 7, Seite 5830-5835
Language:
English
DOI:
10.1039/d3cp05468c
ISSN:
1463-9076;
1463-9084
Origination:
Footnote:
Description:
The spin state of metal centers in catalytic reactions can be rate limiting when high-valent metals such as manganese are involved. Here, we demonstrate dioxidomanganese(v) to be only the second manganese(v) compound to exhibit a high spin state.