• Media type: E-Article
  • Title: Direct spectroscopic evidence for the high-spin state of dioxidomanganese(v)
  • Contributor: Ablyasova, Olesya S.; Zamudio-Bayer, Vicente; Flach, Max; da Silva Santos, Mayara; Lau, J. Tobias; Hirsch, Konstantin
  • Published: Royal Society of Chemistry (RSC), 2024
  • Published in: Physical Chemistry Chemical Physics, 26 (2024) 7, Seite 5830-5835
  • Language: English
  • DOI: 10.1039/d3cp05468c
  • ISSN: 1463-9076; 1463-9084
  • Origination:
  • Footnote:
  • Description: The spin state of metal centers in catalytic reactions can be rate limiting when high-valent metals such as manganese are involved. Here, we demonstrate dioxidomanganese(v) to be only the second manganese(v) compound to exhibit a high spin state.