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Media type:
E-Article
Title:
Investigating structural properties and reaction mechanism of non-stoichiometric spinel LNMO via solid state NMR
Contributor:
Asres, Nahom Enkubahri;
Etxebarria, Naiara;
Monterrubio, Iciar;
Saurel, Damien;
Elkjær, Christian Fink;
Casas-Cabanas, Montse;
Reynaud, Marine;
Fehse, Marcus;
López del Amo, Juan Miguel
Published:
Royal Society of Chemistry (RSC), 2023
Published in:
Journal of Materials Chemistry A, 11 (2023) 46, Seite 25612-25625
Language:
English
DOI:
10.1039/d3ta04649d
ISSN:
2050-7488;
2050-7496
Origination:
Footnote:
Description:
By applying solid-state 6,7Li NMR, we reveal a redox reaction sequence of solid solution and biphasic transition and highlight the existence of intermediate species in non-stoichiometric transition metal-ordered high-voltage LNMO cathode reaction vs. Li.