Weske, Sebastian
[Verfasser:in]
;
Koszinowski, Konrad
[Akademische:r Betreuer:in];
Meyer, Franc
[Akademische:r Betreuer:in]
From copper to gold: identification and characterization of coinage-metal ate complexes by ESI mass spectrometry and gas-Phase fragmentation experiments
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Titel:
From copper to gold: identification and characterization of coinage-metal ate complexes by ESI mass spectrometry and gas-Phase fragmentation experiments
Beschreibung:
Organocuprates are important reagents with numerous applications in preparative organic chemistry, which has led to extensive investigations regarding their molecular composition. However, while lithium organocuprates have been thoroughly studied, the solution speciation of magnesium organocuprates is only poorly understood. Organocuprates have also been proposed as important intermediates in certain copper-mediated trifluoromethylation reactions, but their origin as well as the overall reaction mechanism remained unclear. The higher homologues – organoargentates and -aurates – have been ch...