Beschreibung:
<jats:title>Abstract</jats:title><jats:p>Spinterface engineering has shown quite important roles in organic spintronics as it can improve spin injection or extraction. In this study, 11,11,12,12‐tetracyanonaptho‐2,6‐quinodimethane (TNAP) is introduced as an interfacial layer for a prototype interface of Fe/TNAP. An element‐specific investigation of the electronic and magnetic structures of Fe/TNAP system by use of near edge X‐Ray absorption fine structure (NEXAFS) and X‐ray magnetic circular dichroism (XMCD) is reported. Strong hybridization between TNAP and Fe and induced magnetization of N atoms in TNAP molecule are observed. XMCD sum rule analysis demonstrates that the adsorption of TNAP reduces the spin moment of Fe by 12%. In addition, induced magnetization in N K‐edge of TNAP is also found with other commonly used ferromagnets in organic spintronics, such as La<jats:sub>0.7</jats:sub>Sr<jats:sub>0.3</jats:sub>MnO<jats:sub>3</jats:sub> and permalloy, which makes TNAP a very promising molecule for spinterface engineering in organic spintronics.</jats:p>