University thesis:
Dissertation, Georg-August-Universität Göttingen, 2023
Footnote:
Description:
C-glycosides are widely distributed structural motifs found in natural products and commercially available drug molecules. Due to the stability of glycosidic C-C bonds against chemical and enzymatic hydrolysis, only C-glycosides have been used and synthesized as synthetic substitutes for O-glycosides. Research into the development of stereoselective C-glycosylation for accessing carbohydrate analogs has gained significant importance. However, the precise construction of glycosidic C-C bonds has long been a major challenge in the stereocontrolled synthesis of carbohydrates. In recent years, ...