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Hinterholzinger, Florian M. [Author]; Wuttke, Stefan [Author]; Roy, Pascal [Author]; Preuße, Thomas [Author]; Schaate, Andreas [Author]; Behrens, Peter [Author]; Godt, Adelheid [Author]; Bein, Thomas [Author]

Highly oriented surface-growth and covalent dye labeling of mesoporous metal-organic frameworks - [published Version]

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  • Media type: E-Article; Text
  • Title: Highly oriented surface-growth and covalent dye labeling of mesoporous metal-organic frameworks
  • Contributor: Hinterholzinger, Florian M. [Author]; Wuttke, Stefan [Author]; Roy, Pascal [Author]; Preuße, Thomas [Author]; Schaate, Andreas [Author]; Behrens, Peter [Author]; Godt, Adelheid [Author]; Bein, Thomas [Author]
  • imprint: Cambridge : Royal Society of Chemistry, 2012
  • Published in: Dalton Transactions 41 (2012), Nr. 14
  • Issue: published Version
  • Language: English
  • DOI: https://doi.org/10.15488/2172; https://doi.org/10.1039/c2dt12265k
  • ISSN: 1477-9226
  • Keywords: Covalent attachment ; Fluorescence quenching ; Size-selective ; Dye-labeling ; Pore system ; Metal organic framework ; Mesoporous materials ; Mesoporous ; Fluorescent dyes ; Functional moieties ; Rhodamine B ; Self assembled monolayers ; Fluorescence
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  • Description: Mesoporous amino-functionalized metal-organic framework thin films with the UiO-68 topology were grown in a highly oriented fashion on two different self-assembled monolayers on gold. The oriented MOF films were covalently modified with the fluorescent dye Rhodamine B inside the pore system, as demonstrated with size-selective fluorescence quenching studies. Our study suggests that mesoporous metal-organic frameworks are promising hosts for the covalent attachment of numerous functional moieties in a molecularly designed crystalline environment. © The Royal Society of Chemistry 2012.
  • Access State: Open Access