Nimax, Patrick R.
[Author];
Rotthowe, Nils
[Author];
Zoller, Florian
[Author];
Blockhaus, Tobias
[Author];
Wagner, Fritz
[Author];
Fattakhova, Dina
[Author];
Sünkel, Karlheinz
[Author]
Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide
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Media type:
E-Article
Title:
Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide
Contributor:
Nimax, Patrick R.
[Author];
Rotthowe, Nils
[Author];
Zoller, Florian
[Author];
Blockhaus, Tobias
[Author];
Wagner, Fritz
[Author];
Fattakhova, Dina
[Author];
Sünkel, Karlheinz
[Author]
Published:
Soc., 2021
Published in:Dalton transactions 50(47), 17643 - 17652 (2021). doi:10.1039/D1DT02866A
Footnote:
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Description:
Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(II) and iron(III), silver(I) and potassium(I) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mößbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(I) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer.