You can manage bookmarks using lists, please log in to your user account for this.
Media type:
E-Article
Title:
Atmospheric quenching of vibrationally excited O2(1Δ)
Contributor:
Klais, Odo;
Laufer, Allan H.;
Kurylo, Michael J.
Published:
AIP Publishing, 1980
Published in:
The Journal of Chemical Physics, 73 (1980) 6, Seite 2696-2699
Language:
English
DOI:
10.1063/1.440483
ISSN:
0021-9606;
1089-7690
Origination:
Footnote:
Description:
Flash photolysis of O3 in the Hartley band has been coupled with absorption spectroscopic detection of O2(1Δ, v=0) and resonance fluorescence detection of O(3P) to analyze the fate of O2(1Δ, v?1) in an atmospheric environment. The results indicate a rapid vibrational deactivation under atmospheric conditions. The same analysis permits an estimate of the relative quantum yield of O2(1Δ, v?1) in the photolysis. Similarly, an upper limit for the channel of the O(1D)+O3 reaction yielding O2(1Σ) is derived.