• Media type: E-Article
  • Title: Calculation of resonant states using an optimal path of continuous extension of the bound states: The cubic and quartic energy distortion of the harmonic oscillator
  • Contributor: Jolicard, Georges; Perrin, Marie-Yvonne
  • imprint: AIP Publishing, 1989
  • Published in: The Journal of Chemical Physics
  • Language: English
  • DOI: 10.1063/1.457245
  • ISSN: 0021-9606; 1089-7690
  • Keywords: Physical and Theoretical Chemistry ; General Physics and Astronomy
  • Origination:
  • Footnote:
  • Description: <jats:p>Resonant eigenvectors are calculated within the framework of the complex rotation theory using a continuous deformation and extension of the localized bound states through the potential barrier. The vector is obtained by gradually increasing the basis size and defining for each new basis a lesser perturbation path which best verifies the complex extension of the virial theorem. The modifications resulting from the increase of the basis set N and from the variations of the optimal rotation angle θ(N) are well handled using a Bloch wave operator formulation.</jats:p>