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Media type:
E-Article
Title:
Kinetics of sol–gel transition in thermoreversible gelation of gelatin
Contributor:
Bohidar, Himadri B.;
Jena, Sidhartha S.
imprint:
AIP Publishing, 1993
Published in:The Journal of Chemical Physics
Language:
English
DOI:
10.1063/1.464456
ISSN:
0021-9606;
1089-7690
Origination:
Footnote:
Description:
<jats:p>The sol–gel transition in dilute gels of gelatin are studied by differential scanning calorimetry (DSC) and static light scattering techniques. The sol–gel phase diagram clearly shows the existence of an upper critical solution temperature in this system. In addition, the DSC data conclusively exhibits two more phase curves in the sol state—one pertaining to the coexistence of monomers and aggregates and the second one separating the random coil and helix domains in the solution phase. The Ferry–Eldridge equation has been used to determine the enthalpy of the melting of the gel structure (ΔHg) which is equal to (30±2.0) kcal mol−1. The gelation temperature Tg is correlated to Flory’s statistical model of gelation, which gives the enthalpy of melting of pure gelatin crystallites (ΔHv) as ΔHv=(35±2.0) kcal cm−3 and crystallite melting temperature (Tm) as Tm=(588±20.0) K. The Flory–Huggins interaction parameter (χ) has been determined as χ=0.49±0.05. Interesting scaling behavior has been observed through light scattering measurements. The intensity of scattered light, Is∼ε−γ and Is∼ε0−β; ε=(T/Tg−1); T≥Tg and ε0=(t/tg−1); t≥tg, where t is the time and tg is the gelation time for ε and ε0≤0.5 with γ≂β≂0.02±0.005. The initial phase of cooling of the sol has been analyzed within the framework of Smoluchowski aggregation kinetics. On the basis of the above results it is being proposed that the sol–gel transition path in this polymer has three distinct steps—monomer aggregation, coil–single-helix transition, and single-helix–triple-helix transition followed by gelation.</jats:p>