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Frohn, Hermann‐Josef; Hirschberg, Markus Egon; Westphal, Ulrich; Flörke, Ulrich; Boese, Roland; Bläser, Dieter

First Isolation and Structural Characterization of N‐base Adducts of Mono‐ and Perfluoroaryliodine(III) Compounds, ArfIX2 (X = F, CN)

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  • Media type: E-Article
  • Title: First Isolation and Structural Characterization of N‐base Adducts of Mono‐ and Perfluoroaryliodine(III) Compounds, ArfIX2 (X = F, CN)
  • Contributor: Frohn, Hermann‐Josef; Hirschberg, Markus Egon; Westphal, Ulrich; Flörke, Ulrich; Boese, Roland; Bläser, Dieter
  • Published: Wiley, 2009
  • Published in: Zeitschrift für anorganische und allgemeine Chemie, 635 (2009) 13-14, Seite 2249-2257
  • Language: English
  • DOI: 10.1002/zaac.200900169
  • ISSN: 0044-2313; 1521-3749
  • Keywords: Inorganic Chemistry
  • Origination:
  • Footnote:
  • Description: AbstractThe adducts of aryliodinedifluorides ArfIF2, (Arf = C6F5; x‐FC6H4, x = 2, 3, 4) and aryliodinedicyanide 4‐FC6H4I(CN)2 with N‐bases (phenanthroline, 2,2′‐bipyridine, and quinoline) were isolated and characterized by their single crystal structure, Raman spectra, and their multi nuclear magnetic resonance spectra in solution. Their properties and their thermal decomposition are discussed with respect to the non‐coordinated analogues.