Media type: E-Article Title: Mild C−H/C−C Activation by Z‐Selective Cobalt Catalysis Contributor: Zell, Daniel; Bu, Qingqing; Feldt, Milica; Ackermann, Lutz imprint: Wiley, 2016 Published in: Angewandte Chemie International Edition Language: English DOI: 10.1002/anie.201601778 ISSN: 1433-7851; 1521-3773 Origination: Footnote: Description: <jats:title>Abstract</jats:title><jats:p>Cationic cobalt complexes enable unprecedented cobalt‐catalyzed C−H/C−C functionalizations with unique selectivity features. The versatile cobalt catalyst proved broadly applicable, enabled efficient C−H/C−C cleavage at room temperature, and delivered Z‐alkenes with excellent diastereocontrol.</jats:p>