Description:
<jats:p><jats:bold>Chain Lengthening of Tetrafluoro‐1,2‐ethanedisulfenyl Dichloride by the Reaction with Hydrogen Peroxide</jats:bold></jats:p><jats:p>The reaction of the little compound ClSCF<jats:sub>2</jats:sub>CF<jats:sub>2</jats:sub>SCl (<jats:bold>1</jats:bold>) with aqueous H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> results in the formation of ClS<jats:sub>2</jats:sub>CF<jats:sub>2</jats:sub>CF<jats:sub>2</jats:sub>SSCF<jats:sub>2</jats:sub>CF<jats:sub>2</jats:sub>SO<jats:sub>2</jats:sub>Cl(<jats:bold>2</jats:bold>), which is characterized on the basis of <jats:sup>19</jats:sup>F NMR, mass, IR, and Raman spectroscopy.</jats:p>