• Media type: E-Article
  • Title: ChemInform Abstract: The First Enantioselective [3 + 2] Cycloaddition of Epoxides to Arylisocyanates: Asymmetric Synthesis of Chiral Oxazolidinone Phosphonates
  • Contributor: Barros, Maria Teresa; Faisca Phillips, Ana Maria
  • Published: Wiley, 2011
  • Published in: ChemInform, 42 (2011) 16
  • Language: English
  • DOI: 10.1002/chin.201116192
  • ISSN: 0931-7597; 1522-2667
  • Keywords: General Earth and Planetary Sciences ; General Environmental Science
  • Origination:
  • Footnote:
  • Description: AbstractThe [3 + 2] cycloaddition of phosphonyloxirane (I) with aryl isocyanates (II) is smoothly catalyzed by SmCl3 or YbCl3 to give 5‐substituted oxazolidinone phosphonates (III) with excellent regioselectivity.