Published in:
Chemie Ingenieur Technik, 96 (2024) 5, Seite 658-670
Language:
German
DOI:
10.1002/cite.202300191
ISSN:
0009-286X;
1522-2640
Origination:
Footnote:
Description:
AbstractDiazo compounds are gathering interest for their potential in promoting greener synthesis routes. We investigate, at a lab‐scale, the continuous synthesis of diazo acetonitrile (DAN) using a micro‐structured flow reactor and a flow reaction calorimeter. Data concerning DAN formation in the former, and relative to reaction heat and gas flow rate in the latter, are collected. We present a physical and a grey‐box model, both of which are calibrated to our data. Compared to the physical model, the grey‐box approach allows to better incorporate the complex chemical reaction pathways of DAN.