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Leitner, Tanja D.; Gmeinder, Yannick; Röhricht, Fynn; Herges, Rainer; Mena‐Osteritz, Elena; Bäuerle, Peter

Twisted Thienylene–Phenylene Structures: Through‐Space Orbital Coupling in Toroidal and Catenated Topologies

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  • Media type: E-Article
  • Title: Twisted Thienylene–Phenylene Structures: Through‐Space Orbital Coupling in Toroidal and Catenated Topologies
  • Contributor: Leitner, Tanja D.; Gmeinder, Yannick; Röhricht, Fynn; Herges, Rainer; Mena‐Osteritz, Elena; Bäuerle, Peter
  • imprint: Wiley, 2020
  • Published in: European Journal of Organic Chemistry
  • Language: English
  • DOI: 10.1002/ejoc.201901637
  • ISSN: 1434-193X; 1099-0690
  • Keywords: Organic Chemistry ; Physical and Theoretical Chemistry
  • Origination:
  • Footnote:
  • Description: <jats:p>Sterically crowded and twisted thienylene‐phenylenes were synthesized and characterized in comparison to corresponding polyphenylene nanostructures. Spectroscopic, diffraction, and theoretical studies gave evidence of through‐space delocalization of π‐electrons of peripheral (hetero)aromatic rings in toroidal and catenated topologies.</jats:p>