Media type: E-Article Title: Synthesis of novel 1,3‐substituted 1H‐[1,2,4]‐triazole‐3‐thiol derivatives Contributor: Eliazyan, Karine A.; Shahbazyan, Lusya V.; Pivazyan, Vergine A.; Ghazaryan, Emma A.; Yengoyan, Aleksandr P. imprint: Wiley, 2009 Published in: Heteroatom Chemistry Language: English DOI: 10.1002/hc.20565 ISSN: 1042-7163; 1098-1071 Origination: Footnote: Description: <jats:title>Abstract</jats:title><jats:p>By means of regioselective S‐alkylation of 1H‐1,2,4‐triazole‐3‐thiol (<jats:bold>1</jats:bold>), a series of S‐substituted derivatives <jats:bold>2a‐j</jats:bold> were synthesized. In certain conditions, the reaction of <jats:bold>2</jats:bold> with arylsulfochlorides, arylisocyanates, and quaternary ammonium salts of azines corresponding compounds were obtained 1‐arylsulfonyl‐ <jats:bold>(3a‐d)</jats:bold>, 1‐arylcarbonamido‐ (<jats:bold>4a,b</jats:bold>), and 1‐azinyl‐1,2,4‐ (<jats:bold>6a‐p</jats:bold>) triazoles. Structures of compounds were confirmed by <jats:sup>1</jats:sup>H NMR and elemental analyses. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 20:405–410, 2009; Published online in Wiley InterScience (<jats:ext-link xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="http://www.interscience.wiley.com">www.interscience.wiley.com</jats:ext-link>). DOI 10.1002/hc.20565</jats:p> Access State: Open Access