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Media type:
E-Article
Title:
Monitoring the Microscopic Molecular Mechanisms of Proton Transfer in Acid‐base Reactions in Aqueous Solutions
Contributor:
Pines, Dina;
Nibbering, Erik T. J.;
Pines, Ehud
Published:
Wiley, 2015
Published in:
Israel Journal of Chemistry, 55 (2015) 11-12, Seite 1240-1251
Language:
English
DOI:
10.1002/ijch.201500057
ISSN:
0021-2148;
1869-5868
Origination:
Footnote:
Description:
AbstractThis article provides a review of the authors’ collaborative work on acid‐base reactions under conditions allowing direct observation of mechanistic details of the proton transfer within reactive complexes of OH groups and the bases RCOO− (R=organic residues) in diffusion‐assisted neutralization reactions by using time‐resolved UV/Vis emission and IR absorption spectroscopy. We discuss the considerable insight gained by these experiments and outline the current status of the field.