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Milchert, Eugeniusz; Goc, Waldemar; Meissner, Egbert; Myszkowski, Jerzy

Dehydrochlorination of propylene chlorohydrin with sodium hydroxide and with catholyte

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  • Media type: E-Article
  • Title: Dehydrochlorination of propylene chlorohydrin with sodium hydroxide and with catholyte
  • Contributor: Milchert, Eugeniusz; Goc, Waldemar; Meissner, Egbert; Myszkowski, Jerzy
  • Published: Wiley, 1994
  • Published in: Journal of Chemical Technology & Biotechnology, 61 (1994) 3, Seite 251-254
  • Language: English
  • DOI: 10.1002/jctb.280610312
  • ISSN: 0268-2575; 1097-4660
  • Origination:
  • Footnote:
  • Description: AbstractDehydrochlorination of an aqueous solution of propylene chlorohydrin with sodium hydroxide (12·5 and 30% by weight), with catholyte (5 or 10% by weight NaOH + 14% by weight NaCl) and with milk of lime (15% by weight) were compared. The use of catholyte (10% by weight NaOH + 14% by weight NaCl) enables propylene oxide to be obtained in a yield of 94·3%, with 100% conversion of chlorohydrin. The concentration of 1,2‐propylene glycol in the waste is 0·07% by weight.