• Media type: E-Article
  • Title: BaSO4‐, CaF2‐, and Al‐Maleate‐Derived Nanocomposite Coatings with Excellent Mechanical, Thermal, and Optical Properties
  • Contributor: Khalil, Hazem; Gläsel, Hans‐Jürgen; Köhler, Karl; Hardinghaus, Ferdinand; Buchmeiser, Michael R.
  • imprint: Wiley, 2010
  • Published in: Macromolecular Materials and Engineering
  • Language: English
  • DOI: 10.1002/mame.200900277
  • ISSN: 1438-7492; 1439-2054
  • Keywords: Materials Chemistry ; Polymers and Plastics ; Organic Chemistry ; General Chemical Engineering
  • Origination:
  • Footnote:
  • Description: <jats:title>Abstract</jats:title><jats:p>Acrylate‐based nanocomposite coatings prepared from uniformly sized, nanoscaled inorganic, i.e., BaSO<jats:sub>4</jats:sub>‐ and CaF<jats:sub>2</jats:sub>‐ as well as organometallic, i.e., Al‐maleate‐derived nanoparticles were prepared applying photochemical curing. Excellent mechanical and thermal stability as well as high optical transparency was achieved as compared to standard SiO<jats:sub>2</jats:sub>‐based coatings. The performance of CaF<jats:sub>2</jats:sub>‐based nanocomposites could be further enhanced by addition of nanocorundum. A comprehensive data set on surface and Martens hardness, the penetration depths, glass transition temperatures, and UV–Vis transparency of the final coatings is presented.</jats:p><jats:p><jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/jpeg" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/mgra001.jpg"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text> </jats:p>