• Media type: E-Article
  • Title: Frozen‐In Magnetic Order in Uniaxial Magnetic Gels: Preparation and Physical Properties
  • Contributor: Collin, Dominique; Auernhammer, Günter K.; Gavat, Odile; Martinoty, Philippe; Brand, Helmut R.
  • imprint: Wiley, 2003
  • Published in: Macromolecular Rapid Communications
  • Language: English
  • DOI: 10.1002/marc.200350016
  • ISSN: 1022-1336; 1521-3927
  • Keywords: Materials Chemistry ; Polymers and Plastics ; Organic Chemistry
  • Origination:
  • Footnote:
  • Description: <jats:title>Abstract</jats:title><jats:p>We describe the preparation and characterization of uniaxial magnetic gels. Fibril formation of the embedded magnetic particles generates easily detectable magnetic and optical anisotropies. A finite magnetization is frozen‐in and leads to a ferromagnetic‐like response in small homogeneous external magnetic fields. We present, for the first time, frequency dependent measurements of the shear modulus <jats:italic>G</jats:italic>′. Despite their optical and magnetic anisotropy, the gels are mechanically isotropic.</jats:p><jats:p><jats:boxed-text content-type="graphic" position="anchor"><jats:caption><jats:p>The time‐dependent <jats:italic>G</jats:italic>′ for a ferrogel in the parallel orientation in a homogeneous field of 200 mT.</jats:p></jats:caption><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/gif" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/mgra001.gif"><jats:alt-text>magnified image</jats:alt-text><jats:caption><jats:p>The time‐dependent <jats:italic>G</jats:italic>′ for a ferrogel in the parallel orientation in a homogeneous field of 200 mT.</jats:p></jats:caption></jats:graphic></jats:boxed-text> </jats:p>