Published in:
Macromolecular Rapid Communications, 33 (2012) 13, Seite 1149-1153
Language:
English
DOI:
10.1002/marc.201200020
ISSN:
1022-1336;
1521-3927
Origination:
Footnote:
Description:
AbstractLayer‐by‐layer (LbL) assembly technique is applied for the first time for the preparation of nitrogen‐doped carbon capsules. This approach uses colloid silica as template and two polymeric deposition components, that is, poly(ammonium acrylate) and a poly (ionic liquid) poly(3‐cyanomethyl‐1‐vinylimidazolium bromide), which acts as both the carbon precursor and nitrogen source. Nitrogen‐doped carbon capsules are prepared successfully by polymer wrapping, subsequent carbonization and template removal. The as‐synthesized carbon capsules contain ≈7 wt% of nitrogen and have a structured specific surface area of 423 m2 g−1. Their application as supercapacitor has been briefly introduced. This work proves that LbL assembly methodology is available for preparing carbon structures of complex morphology.