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Media type:
E-Article
Title:
Low volatile monofunctional reactive diluents for radiation curable formulations
Contributor:
Kury, Markus;
Ehrmann, Katharina;
Harakály, György Attila;
Gorsche, Christian;
Liska, Robert
imprint:
Wiley, 2021
Published in:Journal of Polymer Science
Language:
English
DOI:
10.1002/pol.20210171
ISSN:
2642-4169;
2642-4150
Origination:
Footnote:
Description:
<jats:title>Abstract</jats:title><jats:p>In the last decades the importance of UV curable formulations has increased continuously. Their fast curing speed, solvent‐free polymerization conditions, and the formation of hard and highly crosslinked photopolymer networks represent major benefits. Commercial UV resins generally consist of multi‐functional vinyl oligomers, photoinitiators, additives, and reactive diluents. Mono‐ and multi‐functional reactive diluents serve as thinners to lower the overall resin viscosity and to improve processability. However, many monofunctional reactive diluents like isobornyl (meth)acrylate or benzyl (meth)acrylate exhibit high volatility, often already at room temperature. This causes adverse effects such as unpleasant odor, potential health risks, and changing resin composition during processing. A new group of monomers that show high potential for replacing traditional highly volatile reactive diluents are salicylate (meth)acrylates. In this work, salicylate‐based thinners are synthesized, polymerized, and characterized with respect to their viscosity, volatility, thermal stability, photoreactivity, and thermomechanical properties of their homopolymers. Additionally, a first example of their diluting effect in a highly viscous difunctional polyester urethane methacrylate is demonstrated with 30 wt% of a cycloaliphatically and an aromatically substituted salicylate methacrylate. The polymers of the diluted resin exhibit similarly high glass transition temperatures of 110 and 126 °C, which are in the range of the polymers of the undiluted resin.</jats:p>