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Media type:
E-Article
Title:
Biodegradable Polycaprolactone as Ion Solvating Polymer for Solution-Processed Light-Emitting Electrochemical Cells
Contributor:
Jürgensen, Nils;
Zimmermann, Johannes;
Morfa, Anthony John;
Hernandez-Sosa, Gerardo
Published:
Springer Science and Business Media LLC, 2016
Published in:
Scientific Reports, 6 (2016) 1
Language:
English
DOI:
10.1038/srep36643
ISSN:
2045-2322
Origination:
Footnote:
Description:
AbstractIn this work, we demonstrate the use of the biodegradable polymer polycaprolactone (PCL) as the ion solvating polymer in solution-processed light-emitting electrochemical cells (LEC). We show that the inclusion of PCL in the active layer yields higher ionic conductivities and thus contributes to a rapid formation of the dynamic p-i-n junction and reduction of operating voltages. PCL shows no phase separation with the emitter polymer and reduces film roughness. The devices show light-emission at voltages as low as 3.2 V and lifetimes on the order of 30 h operating above 150 cd m−2 with turn-on times <20 s and current and luminous efficacies of 3.2 Cd A−1 and 1.5 lm W−1 respectively.