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Media type:
E-Article
Title:
The synergy effect of rare earth cations on local structure and PL emission in a Ce3+:REPO4(RE = La, Gd, Lu, Y) system
Contributor:
Sun, Congting;
Xue, Dongfeng
imprint:
Royal Society of Chemistry (RSC), 2017
Published in:Dalton Transactions
Language:
English
DOI:
10.1039/c7dt01375b
ISSN:
1477-9226;
1477-9234
Origination:
Footnote:
Description:
<p>The activation of P−O bonding that promotes the phase transition and enhances the PL emission of REPO<sub>4</sub>under the synergy effect of rare earth cations is studied. Anion groups with lower site symmetry coordinated with rare earth cations favor 5d → 4f emission of Ce<sup>3+</sup>.</p>