Media type: E-Article Title: Synthesis of tetra-substituted 5-trifluoromethylpyrazoles via sequential halogenation/palladium-catalyzed C–C and C–N cross-coupling Contributor: Wiethan, Carson; Rosa, Wilian C.; Bonacorso, Helio G.; Stradiotto, Mark imprint: Royal Society of Chemistry (RSC), 2016 Published in: Organic & Biomolecular Chemistry Language: English DOI: 10.1039/c5ob02390d ISSN: 1477-0520; 1477-0539 Origination: Footnote: Description: <p>The assembly of tetra-substituted 5-trifluoromethylpyrazoles is presented, involving palladium-catalyzed Negishi or Buchwald–Hartwig cross-couplings to install carbon or nitrogen-based 4-substituents.</p>