Published in:
Dalton Transactions, 48 (2019) 1, Seite 339-345
Language:
English
DOI:
10.1039/c8dt04417a
ISSN:
1477-9226;
1477-9234
Origination:
Footnote:
Description:
<p>Complexes [Fe(CO)<sub>4</sub>(RPCl<sub>2</sub>)] (<bold>2</bold>) (<bold>a</bold>: R = CPh<sub>3</sub>, <bold>b</bold>: R = <sup>t</sup>Bu) were used to generate the first examples of phosphinidenoid iron(0) complexes [Li(12-crown-4)(solv)<sub>n</sub>][Fe(CO)<sub>4</sub>(RPCl] (<bold>3a,b</bold>), characterized by NMR spectroscopy.</p>