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Burg, Finn; Breitenlechner, Stefan; Jandl, Christian; Bach, Thorsten

Enantioselective oxygenation of exocyclic methylene groups by a manganese porphyrin catalyst with a chiral recognition site

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  • Media type: E-Article
  • Title: Enantioselective oxygenation of exocyclic methylene groups by a manganese porphyrin catalyst with a chiral recognition site
  • Contributor: Burg, Finn; Breitenlechner, Stefan; Jandl, Christian; Bach, Thorsten
  • imprint: Royal Society of Chemistry (RSC), 2020
  • Published in: Chemical Science
  • Language: English
  • DOI: 10.1039/c9sc06089h
  • ISSN: 2041-6520; 2041-6539
  • Origination:
  • Footnote:
  • Description: <p>A Mn porphyrin complex with a remote hydrogen bonding motif induces a high enantioselectivity in the oxygenation of 3-alkylquinolones. Compared to an achiral Mn complex, the site-selectivity was completely altered in favour of less reactive methylene groups.</p>
  • Access State: Open Access