• Media type: E-Article
  • Title: A case study on the conversion of Li/Cl phosphinidenoid into phosphinidene complexes
  • Contributor: Junker, Philip; Qu, Zheng-Wang; Kalisch, Tim; Schnakenburg, Gregor; Espinosa Ferao, Arturo; Streubel, Rainer
  • Published: Royal Society of Chemistry (RSC), 2021
  • Published in: Dalton Transactions, 50 (2021) 2, Seite 739-745
  • Language: English
  • DOI: 10.1039/d0dt03884a
  • ISSN: 1477-9226; 1477-9234
  • Origination:
  • Footnote:
  • Description: <p>Transient, thermally very labile Li/Cl phospinidenoid W(CO)<sub>5</sub> complexes were generated to yield E–H insertion products in THF while Umpolung occurred in toluene that was shown by trapping with terminal alkenes.</p>