You can manage bookmarks using lists, please log in to your user account for this.
Media type:
E-Article
Title:
NH bond activation of ammonia and amines by ditetrelenes: key insights into the stereochemistry of nucleophilic addition
Contributor:
McOnie, Sarah L.;
Özpınar, Gül Altınbaş;
Bourque, Jeremy L.;
Müller, Thomas;
Baines, Kim M.
Published:
Royal Society of Chemistry (RSC), 2021
Published in:
Dalton Transactions, 50 (2021) 47, Seite 17734-17750
Language:
English
DOI:
10.1039/d1dt03739k
ISSN:
1477-9226;
1477-9234
Origination:
Footnote:
Description:
The NH activation of ammonia by tetramesityldisilene takes place in three steps: formation of the anti-ammonia-disilene adduct, inversion at the β-silicon, and intramolecular syn-transfer of the proton to give the syn-product.