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Media type:
E-Article
Title:
Concerted addition of aldehydes to the singlet biradical [P(μ-NTer)]2
Contributor:
Rosenboom, Jan;
Villinger, Alexander;
Schulz, Axel;
Bresien, Jonas
Published:
Royal Society of Chemistry (RSC), 2022
Published in:
Dalton Transactions, 51 (2022) 35, Seite 13479-13487
Language:
English
DOI:
10.1039/d2dt02229j
ISSN:
1477-9226;
1477-9234
Origination:
Footnote:
Description:
The cycloaddition of aldehydes to the singlet biradical [P(μ-NTer)]2is demonstrated experimentally. High-levelab initiocalculations reveal a minimal electronic activation barrier.