• Media type: E-Article
  • Title: Laccase-catalyzed derivatization of 6-aminopenicillanic, 7-aminocephalosporanic and 7-aminodesacetoxycephalosporanic acid
  • Contributor: Mikolasch, Annett; Hammer, Elke; Witt, Sabine; Lindequist, Ulrike
  • Published: Springer Science and Business Media LLC, 2020
  • Published in: AMB Express, 10 (2020) 1
  • Language: English
  • DOI: 10.1186/s13568-020-01117-0
  • ISSN: 2191-0855
  • Origination:
  • Footnote:
  • Description: AbstractTrametes spec. laccase (EC 1.10.3.2.) mediates the oxidative coupling of 6-aminopenicillanic, 7-aminocephalosporanic, and 7-aminodesacetoxycephalosporanic acid with 2,5-dihydroxybenzoic acid derivatives to form new penicillin and cephalosporin structures, respectively. The heteromolecular hybrid dimers are formed by nuclear amination of the p-hydroquinones with the primary amines and inhibited in vitro the growth of Staphylococcus species, including some multidrug-resistant strains.
  • Access State: Open Access