• Media type: E-Article
  • Title: (3R,4R)-(–)-3-Hydroxymethyl-4-phenyl-2-o-toluoyl-1,2,3,4-tetrahydroisoquinoline
  • Contributor: Gzella, Andrzej; Chrzanowska, Maria; Dreas, Agnieszka; Kaczmarek, Michał S.; Woźniak, Zenon
  • Published: International Union of Crystallography (IUCr), 2006
  • Published in: Acta Crystallographica Section E Structure Reports Online, 62 (2006) 5, Seite o1774-o1776
  • Language: Not determined
  • DOI: 10.1107/s1600536806012189
  • ISSN: 1600-5368
  • Origination:
  • Footnote:
  • Description: <jats:p>The absolute configuration of the title compound, C<jats:sub>24</jats:sub>H<jats:sub>23</jats:sub>NO<jats:sub>2</jats:sub>, has been confirmed as 3<jats:italic>R</jats:italic>,4<jats:italic>R</jats:italic>. The hydroxymethyl group and phenyl ring at the asymmetric C atoms exhibit α and β orientations, respectively, and the non-planar heterocyclic ring of the tetrahydroisoquinoline system adopts an envelope conformation. The crystal structure is stabilized through hydrogen bonds.</jats:p>