• Media type: E-Article
  • Title: Low‐Temperature Crack Closure in Fluoride Glass
  • Contributor: Lehman, Richard L.; Hill, Richard E.; Sigel, George H.
  • Published: Wiley, 1989
  • Published in: Journal of the American Ceramic Society, 72 (1989) 3, Seite 474-477
  • Language: English
  • DOI: 10.1111/j.1151-2916.1989.tb06156.x
  • ISSN: 0002-7820; 1551-2916
  • Keywords: Materials Chemistry ; Ceramics and Composites
  • Origination:
  • Footnote:
  • Description: Radial cracks generated in heavy‐metal fluoride glass (HMFG) by Vickers indentation were found to decrease in length as a function of time when exposed to humid environments in the temperature range of 22° to 80°C. Inspection by optical and electron microscopy indicated that the cracks appear to be closing, leaving little or no evidence of the original crack aperture. The effect was observed to increase with time, temperature, and humidity levels for all conditions studied. Possible explanations for this behavior include viscous relaxation of glass in the region of the crack tip, or the generation and transport of a fluoride gel phase to the crack aperture.