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Media type:
E-Article
Title:
Les systèmes eau/ester. I. Etude calorimétrique des systèmes eau/acétate d'alcoyle
Contributor:
Richon, Dominique;
Viallard, André
Published:
Canadian Science Publishing, 1976
Published in:
Canadian Journal of Chemistry, 54 (1976) 16, Seite 2584-2593
Language:
English
DOI:
10.1139/v76-367
ISSN:
0008-4042;
1480-3291
Origination:
Footnote:
Description:
A calorimetric study of alkyl acetate/water systems has been carried out in the complete homogeneous and heterogeneous domain of mole fractions. The sign, intensity, and trends of excess enthalpies and mutual solubilities are discussed.Values of the excess enthalpies for ester/water homogeneous mixtures are used for the determination of partial molar excess enthalpies and enthalpies of "solvation" at infinite dilution.The trends of the thermodynamic quantities in this homologous series are discussed in terms of ester/water interactions.