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Nakanishi, Hiroshi; Yamamoto, Osamu

THE NUCLEAR MAGNETIC RESONANCE STUDY OF EXCHANGING SYSTEMS. III. COPE REARRANGEMENT OF CYCLOOCTATETRAENE DIMER BY 13C NMR TOTAL LINE SHAPE ANALYSIS

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  • Media type: E-Article
  • Title: THE NUCLEAR MAGNETIC RESONANCE STUDY OF EXCHANGING SYSTEMS. III. COPE REARRANGEMENT OF CYCLOOCTATETRAENE DIMER BY 13C NMR TOTAL LINE SHAPE ANALYSIS
  • Contributor: Nakanishi, Hiroshi; Yamamoto, Osamu
  • imprint: Oxford University Press (OUP), 1973
  • Published in: Chemistry Letters
  • Language: English
  • DOI: 10.1246/cl.1973.1273
  • ISSN: 0366-7022; 1348-0715
  • Keywords: General Chemistry
  • Origination:
  • Footnote:
  • Description: <jats:title>Abstract</jats:title> <jats:p>13C NMR spectra of cyclooctatetraene dimer (III) were measured at various temperatures. The complete line shape analysis of temperature dependent spectra was made using the modified Bloch equation method. The activation parameters of the degenerate Cope rearrangement were obtained and were compared with the results obtained by the conventional coalescence temperature method.</jats:p>
  • Access State: Open Access