• Media type: E-Article
  • Title: Degradable Nanocomposites for Fused Filament Fabrication Applications
  • Contributor: Healy, Andrew V.; Waldron, Cathal; Geever, Luke M.; Devine, Declan M.; Lyons, John G.
  • Published: MDPI AG, 2018
  • Published in: Journal of Manufacturing and Materials Processing, 2 (2018) 2, Seite 29
  • Language: English
  • DOI: 10.3390/jmmp2020029
  • ISSN: 2504-4494
  • Origination:
  • Footnote:
  • Description: There has been a substantial increase in the use and development of plastics over the last century. However, due to ever-diminishing petroleum feedstocks and growing concern for the environment, there has been a rise in the use of eco-friendly polymers affording similar properties to that of their depleting counterparts. Poly(ε-caprolactone) is one such polymer. This present study investigates the possibility of developing a degradable nanocomposite, suitable for fused filament fabrication, utilizing hot melt extrusion technology to blend poly(ε-caprolactone), poly(ethylene) oxide and the nanoclay halloysite at loadings of two and six weight percent. The extruded blends were characterized using common polymer testing techniques. The addition of poly(ε-caprolactone) to the poly(ethylene) oxide matrix provided a plasticizing effect which was apparent with the melt flow index and melting point of the blends reducing with an increase in poly(ε-caprolactone) content. Upon reinforcing the matrix with halloysite, there was a significant improvement in mechanical properties. The addition of halloysite significantly increased Young’s modulus 11% and 25% when the loading was two and six percent respectively. Furthermore, it was also possible to produce a filament with the desired properties, diameter 1.75 mm, for fused filament fabrication, with subsequent studies required to evaluate their printability.
  • Access State: Open Access