• Media type: E-Article
  • Title: Synthesis, Spectroscopic, Thermal and Catalytic Properties of Four New Metal (II) Complexes with Selected N- and O-Donor Ligands
  • Contributor: Czylkowska, Agnieszka; Rogalewicz, Bartłomiej; Raducka, Anita; Błaszczyk, Natalia; Maniecki, Tomasz; Wieczorek, Kinga; Mierczyński, Paweł
  • Published: MDPI AG, 2020
  • Published in: Materials, 13 (2020) 14, Seite 3217
  • Language: English
  • DOI: 10.3390/ma13143217
  • ISSN: 1996-1944
  • Origination:
  • Footnote:
  • Description: Four solid compounds with formulae: Co(OAc)2(Im)·H2O (I), Ni(OAc)2(Im)1.5·2H2O (II), Cu2(OAc)4(Im) (III) and Zn(OAc)2(Im)·H2O (IV) (where: Im = 1H-Imidazole) were prepared and characterized by chemical and elemental analysis, powder X-ray diffraction patterns and FTIR spectroscopy. Catalytic properties of each complex for styrene oxidation reaction were investigated. Furthermore, thermal properties of compounds were studied using the TG-DTG and DSC techniques under dry air atmosphere. Additionally, volatile thermal decomposition and fragmentation products were also investigated using the TG-FTIR spectra in air.
  • Access State: Open Access