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Media type:
E-Article
Title:
Facile Synthesis of Light-Switchable Polymers with Diazocine Units in the Main Chain
Contributor:
Li, Shuo;
Bamberg, Katrin;
Lu, Yuzhou;
Sönnichsen, Frank D.;
Staubitz, Anne
Published:
MDPI AG, 2023
Published in:
Polymers, 15 (2023) 5, Seite 1306
Language:
English
DOI:
10.3390/polym15051306
ISSN:
2073-4360
Origination:
Footnote:
Description:
Unlike azobenzene, the photoisomerization behavior of its ethylene-bridged derivative, diazocine, has hardly been explored in synthetic polymers. In this communication, linear photoresponsive poly(thioether)s containing diazocine moieties in the polymer backbone with different spacer lengths are reported. They were synthesized in thiol-ene polyadditions between a diazocine diacrylate and 1,6-hexanedithiol. The diazocine units could be reversibly photoswitched between the (Z)- and (E)-configurations with light at 405 nm and 525 nm, respectively. Based on the chemical structure of the diazocine diacrylates, the resulting polymer chains differed in their thermal relaxation kinetics and molecular weights (7.4 vs. 43 kDa) but maintained a clearly visible photoswitchability in the solid state. Gel permeation chromatography (GPC) measurements indicated a hydrodynamic size expansion of the individual polymer coils as a result of the Z→E pincer-like diazocine switching motion on a molecular scale. Our work establishes diazocine as an elongating actuator that can be used in macromolecular systems and smart materials.