The Zugspitze radiative closure experiment for quantifying water vapor
absorption over the terrestrial and solar infrared –
Part 3: Quantification of the mid- and near-infrared water vapor continuum
in the 2500 to 7800 cm<sup>−1</sup> spectral range under atmospheric conditions
You can manage bookmarks using lists, please log in to your user account for this.
Media type:
E-Article
Title:
The Zugspitze radiative closure experiment for quantifying water vapor
absorption over the terrestrial and solar infrared –
Part 3: Quantification of the mid- and near-infrared water vapor continuum
in the 2500 to 7800 cm<sup>−1</sup> spectral range under atmospheric conditions
Contributor:
Reichert, Andreas;
Sussmann, Ralf
imprint:
Copernicus GmbH, 2016
Published in:Atmospheric Chemistry and Physics
Language:
English
DOI:
10.5194/acp-16-11671-2016
ISSN:
1680-7324
Origination:
Footnote:
Description:
<jats:p>Abstract. We present a first quantification of the near-infrared (NIR) water vapor continuum absorption from an atmospheric radiative closure experiment carried out at the Zugspitze (47.42° N, 10.98° E; 2964 m a.s.l.). Continuum quantification is achieved via radiative closure using radiometrically calibrated solar Fourier transform infrared (FTIR) absorption spectra covering the 2500 to 7800 cm−1 spectral range. The dry atmospheric conditions at the Zugspitze site (IWV 1.4 to 3.3 mm) enable continuum quantification even within water vapor absorption bands, while upper limits for continuum absorption can be provided in the centers of window regions. Throughout 75 % of the 2500 to 7800 cm−1 spectral range, the Zugspitze results agree within our estimated uncertainty with the widely used MT_CKD 2.5.2 model (Mlawer et al., 2012). In the wings of water vapor absorption bands, our measurements indicate about 2–5 times stronger continuum absorption than MT_CKD, namely in the 2800 to 3000 cm−1 and 4100 to 4200 cm−1 spectral ranges. The measurements are consistent with the laboratory measurements of Mondelain et al. (2015), which rely on cavity ring-down spectroscopy (CDRS), and the calorimetric–interferometric measurements of Bicknell et al. (2006). Compared to the recent FTIR laboratory studies of Ptashnik et al. (2012, 2013), our measurements are consistent within the estimated errors throughout most of the spectral range. However, in the wings of water vapor absorption bands our measurements indicate typically 2–3 times weaker continuum absorption under atmospheric conditions, namely in the 3200 to 3400, 4050 to 4200, and 6950 to 7050 cm−1 spectral regions.
</jats:p>