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Medientyp:
E-Book
Titel:
Formation and properties of clay-polymer complexes
Enthält:
Front Cover; Formation and Properties of Clay-Polymer Complexes; Copyright; Dedication; Contents; Preface to the First Edition; References; Preface to the Second Edition; Reference; Part I: Clay Minerals and Polymer Adsorption; Chapter 1: The Clay Minerals; 1.1. Structural Aspects; 1.1.1. Planar 1:1 Phyllosilicates; 1.1.1.1. Kaolinite; 1.1.1.2. Halloysite; 1.1.2. Planar 2:1 Phyllosilicates; 1.1.2.1. Smectite; 1.1.2.2. Vermiculite; 1.1.2.3. Mica, Illite and Chlorite; 1.1.3. Non-planar Phyllosilicates; 1.1.3.1. Sepiolite and Palygorskite; 1.1.3.2. Allophane and Imogolite
1.2. Clay-water interactions and clay swellingReferences; Chapter 2: Polymer Behaviour at Clay and Solid Surfaces; 2.1. Introduction; 2.2. Adsorption isotherms; 2.3. Theoretical aspects; 2.4. Colloid chemical aspects; References; Part II: Interactions of Clay Minerals with Synthetic Polymers; Chapter 3: Uncharged (Nonionic) Polymers; 3.1. Introduction; 3.2. Formation and properties of complexes; 3.2.1. Complexes with Poly(vinyl alcohol); 3.2.2. Complexes with (Uncharged) Polyacrylamide; 3.2.3. Complexes with Polyethylene glycol and Polyethylene oxide: Entropy Effects
3.2.4. Complexes with Polyvinyl pyrrolidoneReferences; Chapter 4: Negatively Charged Polymers (Polyanions); 4.1. Introduction; 4.2. Formation and properties of complexes; References; Chapter 5: Positively Charged Polymers (Polycations); 5.1. Introduction; 5.2. Formation and properties of complexes; References; Chapter 6: Some Practical Applications of the Clay-Polymer Interaction; 6.1. Introduction; 6.2. Soil conditioning and clay/soil aggregate stabilization; 6.3. Clays and clay minerals as fillers of polymer systems; 6.3.1. Filler Surface Modification; 6.3.1.1. Organic Modification
6.3.1.2. Silanization6.3.1.3. Polymer Grafting; 6.3.2. Reinforcement of Natural and Synthetic Polymers; 6.3.3. Papermaking; References; Chapter 7: Polymer-Clay Nanocomposites; 7.1. Introduction; 7.2. Surface modification of clay minerals; 7.3. Preparation of polymer-clay nanocomposites; 7.3.1. Intercalation of Polymers from Solution; 7.3.2. Intercalation of Polymers from the Melt; 7.3.3. In Situ Intercalative Polymerization (of Monomers); 7.3.4. Template Synthesis; 7.3.5. Nanocomposites with Phyllosilicates Other than Smectite; 7.4. Concluding remarks; References
Part III: Interactions of Clay Minerals with Naturally Occurring PolymersChapter 8: Proteins and Enzymes; 8.1. Introduction; 8.2. General aspects of the clay-protein interaction; 8.3. Formation and properties of complexes; 8.4. Complex formation and enzyme activity; 8.5. Enzyme behaviour in soil; References; Chapter 9. Nucleic Acids; 9.1. Introduction; 9.2. Formation and properties of complexes; References; Chapter 10. Viruses and Bacteriophages; 10.1. Introduction; 10.2. Formation and properties of complexes; References; Chapter 11. Polysaccharides; 11.1. Introduction
11.2. General aspects of the clay-polysaccharide interaction
Anmerkungen:
Includes bibliographical references and indexes
Beschreibung:
This book provides a comprehensive account of the reactions between clay minerals and organic polymers. The book opens with a discussion of the structures of common clay minerals, clays colloid chemistry, and the behaviour of organic polymers at clay surfaces. This is followed by a systematic treatment of complex formation between clay minerals and various classes of synthetic and naturally occurring polymers, a description of the properties of the resulting complexes and, wherever appropriate, their practical applications. The book will have a new separate chapter on clay-polymer nanocomposit