The thermodynamics of phase and reaction equilibria

Medientyp: E-Book

Titel: The thermodynamics of phase and reaction equilibria

Enthält: Front Cover; The Thermodynamics of Phaseand Reaction Equilibria; Copyright; Dedication; Contents; Preface; Notation; Review of the First and Second Lawsof Thermodynamics; 1.1 Definitions; 1.1.1 System; 1.1.2 Property and State; 1.1.3 Equilibrium; 1.2 Concepts of the ``Abstract World'' of Thermodynamics; 1.2.1 State and Path Functions; 1.2.2 Reversible Process; 1.2.3 General Approach Used in the Solution of Thermodynamics Problems; 1.3 Work; 1.4 Paths Followed During a Process; 1.5 The First Law of Thermodynamics; 1.5.1 Simplification of the Energy Balance; 1.5.1.1 Isolated System
1.5.1.2 Closed System1.5.1.3 Steady-State Flow System; 1.6 The Second Law of Thermodynamics; 1.6.1 Simplification of the Entropy Balance; 1.6.1.1 Isolated System; 1.6.1.2 Closed System; 1.6.1.3 Steady-State Flow System; Reference; Thermodynamic Properties of RealSubstances; 2.1 Work Functions; 2.2 Thermodynamic Properties of a Single-Phase System; 2.2.1 Fundamental Equations; 2.2.2 Maxwell Relations; 2.2.3 Internal Energy Change; 2.2.4 Enthalpy Change; 2.2.5 Entropy Change; 2.2.6 Relationship Between Partial Derivatives; 2.2.7 Relationship Between Heat Capacities
2.2.8 Coefficient of Thermal Expansion and Isothermal CompressibilityReference; Calculation of Changes in InternalEnergy, Enthalpy, and Entropy; 3.1 Equations of State; 3.1.1 Ideal Gas Equation of State; 3.1.2 The Virial Equation of State; 3.1.3 Cubic Equations of State; 3.2 Calculation of the Change in Internal Energy; 3.2.1 Change in Internal Energy for Liquids and Solids; 3.2.2 Change in Internal Energy for Gases; 3.3 Calculation of the Change in Enthalpy; 3.3.1 Change in Enthalpy for Liquids and Solids; 3.3.2 Change in Enthalpy for Gases; 3.4 Calculation of the Change in Entropy
3.4.1 Change in Entropy for Liquids and Solids3.4.2 Change in Entropy for Gases; 3.5 The Principle of Corresponding States; 3.6 Departure Functions; 3.6.1 Departure Functions from the Cubic Equations of State; 3.6.2 Departure Functions from the Principle of Corresponding States; 3.7 Which Equation of State to Use?; References; Equilibrium and Phase Stabilityin One-Component Systems; 4.1 Equilibrium Criteria for Closed Systems; 4.1.1 Condition of Maximum Entropy; 4.1.2 Condition of Minimum Internal Energy; 4.1.3 Condition of Minimum Helmholtz Energy; 4.1.4 Condition of Minimum Gibbs Energy
4.2 Equilibrium Criteria for Open Systems4.3 Phase Stability; 4.3.1 Change of Gibbs Energy with Pressure; 4.3.2 Change of Gibbs Energy with Temperature; Reference; Fugacity of a Pure Component; 5.1 Molar Gibbs Energy of a Pure Ideal Gas; 5.2 Definition of Fugacity and Fugacity Coefficient; 5.3 Fugacity of a Pure Gas; 5.3.1 Fugacity from Volume-Explicit Equations of State; 5.3.2 Fugacity from Property Tables; 5.3.3 Fugacity from the Virial Equation of State; 5.3.4 Fugacity from Cubic Equations of State; 5.3.5 Fugacity from the Principle of Corresponding States; 5.4 Fugacity of a Pure Liquid
5.4.1 Fugacity from Cubic Equations of State

Beteiligte: Tosun, İsmail [VerfasserIn]

Erschienen: Amsterdam; Boston: Elsevier, 2013
Online-Ausg.

Ausgabe: 1st ed.

Umfang: Online Ressource (560 pages); illustrations

Sprache: Englisch

ISBN: 0444594973; 9780444594976

Schlagwörter: Thermodynamik > Chemisches Gleichgewicht > Phasengleichgewicht > Thermochemie

Art der Reproduktion: Online-Ausg.

Entstehung:

Anmerkungen: Description based on print version record

Beschreibung: This book provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g. partial molar Gibbs energy, fugacity, and activity), and shows how to apply these concepts to solve practical problems using numerous clear examples. It also presents numerical methods necessary for solving real-world problems as well the basic mathematics needed, facilitating its use as a self-study reference work. In the example problems requiring MATHCAD® for the solution, the results of the intermediate steps are given, enabling the reader to easily track mistakes and understand the order of magnitude of the various quantities involved. Clear layout, coherent and logical organization of the content, and presentation suitable for self-studyProvides analytical equations in dimensionless form for the calculation of changes in internal energy, enthalpy, and entropy as well as departure functions and fugacity coefficients Includes up-to-date information, comprehensive in-depth content and current examples in each chapter Includes many well organized problems (with answers), which are extensions of the examples enabling conceptual understanding for quantitative/real problem solving Includes the mathematical background required for solving problems encountered in phase and reaction equilibria Provides an instructor's solutions manual

The thermodynamics of phase and reaction equilibria - [1st ed.]

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