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Medientyp:
E-Book
Titel:
Simultaneous Co2 Mineral Sequestration and Rutile Beneficiation by Using Titanium-Bearing Blast Furnace Slag
:
Process Description and Optimization
Beschreibung:
CO 2 mineral sequestration is a promising method for abating global warming. Mineral carbonation with titanium-bearing blast furnace slag (TBFS) can offer a sustainable option for simultaneous CO 2 emission reduction and comprehensive utilization of solid waste. In this study, a novel process combining CO 2 mineral sequestration and rutile beneficiation was proposed by using TBFS and copperas as feedstocks. TBFS and copperas were roasted at 550~750°C to convert the calcium and magnesium into the corresponding sulfates, while titanium in the TBFS was beneficiated to rutile. The roasted slag was then subjected to carbonation followed by recovery of rutile and hematite through flotation and magnetic separation, respectively. The effects of process parameters on sulfation and carbonation units were studied systematically; the optimum roasting conditions were as follows: temperature of 650 °C, copperas to TBFS mass ratio of 2:1 and roasting time of 4 hours. Based on the optimal reaction conditions, it was found that the addition of Na 2 SO 4 can significantly enhance the conversion efficiency of Ti (from 53.47% to 98.37%). The mechanism revealed that the addition of Na 2 SO 4 promoted the formation of molten Na 3 Fe(SO 4 ) 3 , and gas-liquid-solid reactions proceeded much faster and efficiently. The carbonation of sulfated TBFS results indicated that the optimal CO 2 storage capacity can reach 187 kg·t -1 TBFS. In this process, two solid wastes were utilized for CO 2 mineralization, realizing the multiple benefits of CO 2 emission reduction, solid waste disposal as well as valuable byproducts recovery