Beschreibung:
Owing to their electrophilic sulfur atom nearly any nucleophile can be added to the sulfurimides, yielding a variety of diimidosulfinates and triimidosulfonates. This trait opens up a lot of possible synthetic pathways to obtain different ligands. This ligands can be used to form bimetallic complexes. Different approaches to synthesize this bimetallic complexes were investigated in this work. Furthermore it was examined how flexible the ligands react to the requirements of organic groups with variable steric demand. Since the coordination capabilities of the pending imido group in triimidosulfonates have not been investigated in detail, this lack of knowledge was also filled during this work. Besides the described chemical experiments, a new X-ray source was tested ...