Versäumer, Marina
[Verfasser:in]
;
Clever, Guido
[Akademische:r Betreuer:in];
Clever, Guido
[Sonstige Person, Familie und Körperschaft];
Meyer, Franc
[Sonstige Person, Familie und Körperschaft]
Supramolecular coordination cages based on bispyridyl-ligands with redox properties
Beschreibung:
This thesis explores the self-assembly, the host-guest chemistry and the redox behavior of novel coordination double-cages based on organic bispyridyl ligands and Pd(II) metal ions. The formation of these double-cages depends on the interplay of many factors, such as solvent, temperature, metal coordination sites, length and shape of ligands, counter anions and guest molecules. These new three-dimensional architectures with nanoscopic size are of special interest for numerous potential applications, in particular for usage as molecular sensors, as nanoreactors or in photoelectronic devices....