Erschienen in:
The Journal of Chemical Physics, 158 (2023) 24
Sprache:
Englisch
DOI:
10.1063/5.0151752
ISSN:
0021-9606;
1089-7690
Entstehung:
Anmerkungen:
Beschreibung:
We investigate the non-equilibrium fluctuations occurring during free diffusion between two solutions of glycerol and water with various concentration differences. The non-linearity of the system, determined by the strong stratification of the sample, requires introducing an interpretation model able to characterize the dependence of the correlation properties of the non-equilibrium fluctuations on the local thermophysical variables of the system. The proposed model allows us to characterize the dynamics of non-equilibrium fluctuations in the presence of a wide range of relaxation times determined by the strong stratification of the sample, at variance with the cumulant methods commonly used in dynamic light scattering experiments, which work well in the presence of a moderate dispersion of relaxation times.