• Medientyp: E-Artikel
  • Titel: Viscosity and Its Temperature Dependence in Molten BeF2
  • Beteiligte: Moynihan, Cornelius T.; Cantor, Stanley
  • Erschienen: AIP Publishing, 1968
  • Erschienen in: The Journal of Chemical Physics, 48 (1968) 1, Seite 115-119
  • Sprache: Englisch
  • DOI: 10.1063/1.1664455
  • ISSN: 1089-7690; 0021-9606
  • Schlagwörter: Physical and Theoretical Chemistry ; General Physics and Astronomy
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  • Beschreibung: <jats:p>The viscosity of molten beryllium fluoride has been measured with coaxial-cylinder viscometers over five orders of magnitude (limits: 979°C, 28.6 P; 574°C, 2.24 × 106 P). Over the experimental range of shear stresses, BeF2 behaves as a Newtonian fluid. Like SiO2, its high-temperature analog, BeF2 shows an Arrhenius temperature dependence over several orders of magnitude in viscosity. Reported heat-capacity data for BeF2 and SiO2 and the Adam-Gibbs theory indicate that the Arrhenius viscosity behavior of these liquids may be explained in terms of the configurational entropy which is virtually constant at temperatures above the glass-transition temperature.</jats:p>