• Medientyp: E-Artikel
  • Titel: Dielectric constant, refractive index, atomic polarization, and dipole moment derivatives of hexamethylenetetramine-h12 and -d12
  • Beteiligte: Bertie, John E.; Solinas, Marco
  • Erschienen: AIP Publishing, 1974
  • Erschienen in: The Journal of Chemical Physics
  • Sprache: Englisch
  • DOI: 10.1063/1.1682161
  • ISSN: 0021-9606; 1089-7690
  • Schlagwörter: Physical and Theoretical Chemistry ; General Physics and Astronomy
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  • Beschreibung: <jats:p>The frequencies of the longitudinal and transverse components of the infrared-active modes of hexamethylenetetramine-h12 and -d12 have been used to determine the static dielectric constant and the dipole moment derivatives, using the refractive index. The sodium-D refractive index and the static dielectric constant of HMT-d12 are the same as those of HMT-h12, within experimental error. The static dielectric constant is 2.67±0.05 and the atomic polarization is 2.8 ±0.7 cm3. The dipole moment derivatives are listed for seven of the nine infrared-active modes of each molecule.</jats:p>